Beitraege zur Orthopaedie und Traumatologic (German Democratic. Brown, Boranes in Organic Chemistry (Cornell Univ. Vestsi Akademii Navuk BSSR, Seryya Biyalagichnykh Navuk. Tipper (Elsevier Scientific Publishing Co., Amsterdam, 1973).Į. 12, Electrophilic Substitution at a Saturated Carbon A tom, ed. Abraham, Comprehensive Chemical Kinetics, vol. Beletskaya, Reaction Mechanisms of Organometallic Compounds (North-Holland Press, Amsterdam, 1968). Rickborn, Electrophilic Substitution of Organomercurials (McGraw-Hill, New York, 1968). Methoden der Organischen Chemie Band XIII/2b Metallorganische Verbindungen: Hg, Georg. Kocheshkov (North-Holland Press, Amsterdam, 1967). Electron-donor ability of bis-cyclopentadienyl derivatives of tungsten (AlkC 5 H 4) 2 WX 2 (Alk Me, Et, n-Pr, n-Bu, i-Pr, t-Bu X Cl, Br, I), towards the strong -acids tetracyanoethylene and 7,7,8,8-tetracyanoquinodimethane, has been studied using the method of UV absorption spectroscopy. Nesmeyanov, Methods of Elemento-Organic Chemistry, vol. Whitmore (1921), Organic Compounds of Mercury (Chemical Catalog Company Inc., New York). ![]() This process is experimental and the keywords may be updated as the learning algorithm improves. These keywords were added by machine and not by the authors. Thus reactions of the Hg-X bond in organomercurials of the type RHgX are considered only in as much as they provide a route to new compounds in the same series (RHgY) and to the fully organic mercurials (R 2Hg). Homocyclic silicon compounds Cyclotetrasilanes Cyclohexasilanes II. Further, in the belief that it is the metal-carbon interaction that is of central interest in organometallic chemistry, our treatment of organomercury reactions is concentrated on those involving the mercury-carbon bond. 546.28 Institute of Organoelemental Compounds, Academy of Sciences of the USSR INORGANIC CYCLIC SILICON-CONTAINING COMPOUNDS AND THEIR ORGANIC DERIVATIVES K. Thus compounds such as Hg(OPr) 2, Hg(NEt 2) 2 or Hg(SiMe 3) 2 in which mercury is attached to some other atom of an organic moiety are regarded as inorganic mercurials and are not considered here. We have taken the view that organomercury compounds are species in which there is bonding between mercury and organic carbon. ![]() There is general agreement as to what constitutes an organic compound, but what is encompassed by the term ‘organometallic’ is more controversial.
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